Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5934
DC FieldValueLanguage
dc.contributor.authorCappelli, Andreaen_us
dc.contributor.authorPaolino, Marcoen_us
dc.contributor.authorGrisci, Giorgioen_us
dc.contributor.authorGiuliani, Germanoen_us
dc.contributor.authorDonati, Alessandroen_us
dc.contributor.authorR., Mendichien_us
dc.contributor.authorA. C., Bocciaen_us
dc.contributor.authorF., Samperien_us
dc.contributor.authorS., Battiatoen_us
dc.contributor.authorPaccagnini, Eugenioen_us
dc.contributor.authorGiacomello, Emilianaen_us
dc.contributor.authorSorrentino, Vincenzoen_us
dc.contributor.authorM., Licciardien_us
dc.contributor.authorG., Giammonaen_us
dc.contributor.authorVomero, Salvatoreen_us
dc.date.accessioned2021-03-30T15:56:13Z-
dc.date.available2021-03-30T15:56:13Z-
dc.date.issued2011-
dc.identifier.issn1759-9954en_US
dc.identifier.urihttp://hdl.handle.net/20.500.12779/5934-
dc.description21843en_US
dc.description.abstractA new biorelevant polymer brush showing a polybenzofulvene backbone was synthesized by a ‘‘graftingthrough’’ approach based on click chemistry and spontaneous polymerization reactions. The easypolymerization of the relatively complex monomer (6-MOEG-9-TM-BF3k) suggests the existence ofa particularly efficient recognition process capable of pre-organizing the monomer molecules for thespontaneous polymerization. 13C-NMR spectroscopy as well as UV-vis and fluorescence spectroscopysuggested for poly-6-MOEG-9-TM-BF3k the features of a vinyl (1,2) p-stacked polymer. The newpolybenzofulvene derivative was found to interact with water at room temperature to give clear watersolutions, but TEM analysis demonstrated the presence of macromolecular aggregates showingdimensions larger than those suggested by SEC-MALS analysis for the isolated macromolecules. DLSstudies confirmed the presence of objects showing average dimensions in the range of 200–300 nm andsuggested thermoresponsive colloidal properties for poly-6-MOEG-9-TM-BF3k macromolecules.Finally, owing to its favourable absorption/emission properties and water solubility, the interaction ofpoly-6-MOEG-9-TM-BF3k with live cells was studied by fluorescence microscopy experiments, whichrevealed that the polymer brush was unable to enter live cells and alter cell morphology.en_US
dc.language.isoenen_US
dc.relationNoneen_US
dc.relation.ispartofPOLYMER CHEMISTRYen_US
dc.titleA Click Chemistry-Based “Grafting Through” Approach to the Synthesis of a Biorelevant Polymer Brushen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c1py00271fen_US
dc.identifier.scopus2-s2.0-80054017190en_US
dc.identifier.isiWOS:000295811400011en_US
dc.relation.volume2en_US
dc.description.firstpage2518en_US
dc.description.lastpage2527en_US
dc.description.thirdmissionNot applicableen_US
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeArticle-
item.fulltextNo Fulltext-
crisitem.author.orcid0000-0003-4140-3028-
crisitem.author.orcid0000-0003-1387-7875-
crisitem.author.orcid0000-0001-8111-3776-
crisitem.author.orcid0000-0001-5130-2154-
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