Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5643
DC FieldValueLanguage
dc.contributor.authorBuchalski, P.en_us
dc.contributor.authorKaminska, E.en_us
dc.contributor.authorPiwowar, K.en_us
dc.contributor.authorSuwinska, K.en_us
dc.contributor.authorJerzykiewicz, L.en_us
dc.contributor.authorRossi, F.en_us
dc.contributor.authorLaschi, Francoen_us
dc.contributor.authorFabrizi De Biani, Fabriziaen_us
dc.contributor.authorZanello, Pieroen_us
dc.date.accessioned2021-03-30T15:54:04Z-
dc.date.available2021-03-30T15:54:04Z-
dc.date.issued2009-
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/20.500.12779/5643-
dc.description40140en_US
dc.description.abstractReactions of 9-nickelafluorenyllithium with cobalt and nickel pentamethylcyclopentadienyl-acetylacetonates resulted in the formation of the novel nickelacyclic-cobaltocene 2 and nickelacyclic-nickelocene 3, respectively, in which the central metal atom is bonded to the nickelafluorenyl ring. On the basis of their redox propensity, compounds 2 and 3 were oxidized to the corresponding monocations [2]+ and [3]+. The crystal and molecular structures of both the redox couples were determined by single-crystal X-ray analysis. In spite of their structural similarity, they display a rather different electron transfer ability. To throw light on such an aspect, the pertinent redox couples have been examined by EPR spectroscopy and the nature of the frontier orbitals involved in the redox activity of the neutral precursors has been supported by extended Hückel theoretical calculations.en_US
dc.language.isoenen_US
dc.relationNoneen_US
dc.relation.ispartofINORGANIC CHEMISTRYen_US
dc.titleNickelacyclic-Cobaltocene vs. Nickelacyclic-Nickelocene. Synthesis, X-ray Structures, Electron Transfer Activity, EPR Spectroscopy, and Theoretical Calculationsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ic900329wen_US
dc.identifier.scopus2-s2.0-66249133656en_US
dc.identifier.isiWOS:000266428100055en_US
dc.relation.volume48en_US
dc.description.firstpage4934en_US
dc.description.lastpage4941en_US
dc.description.thirdmissionNot applicableen_US
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeArticle-
item.fulltextNo Fulltext-
crisitem.author.orcid0000-0002-1698-5858-
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