Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5596
Title: Stereoselective protecting group free synthesis of D,L-gulose ethyl glycoside via multicomponent enyne cross methatesis-hetero Diels-Alder reaction
Authors: Castagnolo, Daniele
Botta, Lorenzo
Botta, Maurizio 
Keywords: Gulose; Stereoselective synthesis; Microwave; Hexose
Issue Date: 2009
Project: None 
Journal: CARBOHYDRATE RESEARCH
Abstract: 
An efficient and stereoselective synthesis of D,L-gulose was described. The key step of the synthetic route is represented by a multicomponent enyne cross metathesis-hetero Diels-Alder reaction which allows the formation of the pyran ring from cheap and commercially available substrates in a single synthetic step. The synthesis of D,L-gulose was accomplished without the use of protecting groups making this approach highly desirable also in terms of atom economy.
Description: 
22251
URI: http://hdl.handle.net/20.500.12779/5596
ISSN: 0008-6215
DOI: 10.1016/j.carres.2009.05.007
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