Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5587
Title: Fluorenylidene-Pyrroline Biomimetic Ligth -Driven Molecular Switches
Authors: RIVADO CASAS, L
Sampedro, D
CAMPOS P., J
Fusi, Stefania 
Zanirato, V
Olivucci, Massimo 
Issue Date: 2009
Project: None 
Journal: JOURNAL OF ORGANIC CHEMISTRY
Abstract: 
A new family of biomimetic photoactivated molecular switches based in the retinal chromophore is described. Expedient synthesis allows a library of compounds with a different substitution pattern, including chiral substituents, to be obtained. The effect of substitution, solvent, and light source on thephotoisomerization step has been assessed. The absorption maximum has been red-shifted ca. 50 nmwith respect to related systems and rotation is now easily achieved by using visible light.
Description: 
38128
URI: http://hdl.handle.net/20.500.12779/5587
ISSN: 0022-3263
DOI: 10.1021/jo802792j
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