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|Title:||The redox behavior of 9-nickelafluorenyl sandwich complexes||Authors:||Rossi, F.
Fabrizi De Biani, Fabrizia
|Issue Date:||2009||Project:||None||Journal:||JOURNAL OF SOLID STATE ELECTROCHEMISTRY||Abstract:||
A collection of nickelocene and cobaltocene analogs with one or two nickelafluorenyl rings has been recently synthesized starting from 9-nickelafluorenyllithium complex. The redox ability of the whole series of derivates has been investigated by electrochemical techniques, and the nature of the frontier orbitals responsible for the electron transfer activity of this class of compounds has been supported by extended Hückel calculations.
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