Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5444
DC FieldValueLanguage
dc.contributor.authorFabrizi De Biani, Fabriziaen_us
dc.contributor.authorGrigiotti, E.en_us
dc.contributor.authorLaschi, Francoen_us
dc.contributor.authorZanello, Pieroen_us
dc.contributor.authorJuris, A.en_us
dc.contributor.authorProdi, L.en_us
dc.contributor.authorChichak, K. S.en_us
dc.contributor.authorBranda, N. R.en_us
dc.date.accessioned2021-03-30T15:51:42Z-
dc.date.available2021-03-30T15:51:42Z-
dc.date.issued2008-
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://hdl.handle.net/20.500.12779/5444-
dc.description40177en_US
dc.description.abstractA series of mixed-metal supramolecular porphyrin arrays in which the geometry of the central metal-polypyridyl moiety defines the spatial arrangement of two or more Ru(II)-porphyrin units through axial coordination have been prepared by employing self-assembly based protocols, and their photophysical and electrochemical properties have been studied. The electrochemical properties of the constituent parts of these arrays depend only on their own chemical environment, regardless of the nuclearity and the overall charge of the compound; in this way species with predetermined redox patterns can be obtained via the synthetic control of the self-assembly process. Interestingly, several of these arrays are luminescent both at room and at low temperatures, and in many cases core-to-periphery or periphery-to-core intramolecular energy transfer processes take place according to the nature of the central metal template.en_US
dc.language.isoenen_US
dc.relationNoneen_US
dc.relation.ispartofINORGANIC CHEMISTRYen_US
dc.titleSupramolecular metal-polypyridyl and Ru(II) porphyrin complexes: Photophysical, electron paramagnetic resonance, and electrochemical studiesen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ic7018428en_US
dc.identifier.scopus2-s2.0-46949099990en_US
dc.identifier.isiWOS:000256591400050en_US
dc.relation.volume47en_US
dc.description.firstpage5425en_US
dc.description.lastpage5440en_US
dc.description.thirdmissionNot applicableen_US
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeArticle-
item.fulltextNo Fulltext-
crisitem.author.orcid0000-0002-1698-5858-
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