Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5166
Title: Flattened Cone 2,8,14,20-Tetrakis(l-valinamido)-[4]resorcinarene: An Enantioselective Allosteric Receptor in the Gas Phase
Authors: B., Botta
F., Caporuscio
D., Subissati
Tafi, Andrea 
Botta, Maurizio 
A., Filippi
M., Speranza
Issue Date: 2006
Project: None 
Journal: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Abstract: 
Displacement of the enantiomers of tryptophan from the achiral hydrophobic rim of a flattened cone resorcinarene derivative is induced by 2-aminobutane (B). The displacement exhibits a marked enantioselectivity which is traced to a conformational coupling between the achiral hydrophobic rim of the resorcinarene host and its chiral hydrophilic rim wherein the 2-aminobutane enantiomers are trapped.
Description: 
19432
URI: http://hdl.handle.net/20.500.12779/5166
ISSN: 1433-7851
DOI: 10.1002/anie.200503987
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