Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5059
Title: SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMICAL BEHAVIOR OF MONO- AND BIMETALLIC RUTHENIUM AND RHENIUM ALLENYLIDENES BEARING MULTICONJUGATED ORGANIC SPACERS
Authors: N., Mantovani
M., Brugnati
L., Gonsalvi
E., Grigiotti
Laschi, Franco 
L., Marvelli
M., Peruzzini
G., Reginato
R., Rossi
P., Zanello
Issue Date: 2005
Project: None 
Journal: ORGANOMETALLICS
Abstract: 
Novel monoallenylidenes of Ru and Re and homobimetallic Ru/Ru and heterobimetallic Ru/Re complexes bridged by multiconjugated aromatic organic spacers such as bianthracenylidene and biphenylene were obtained and characterized by conventional spectroscopic techniques and elemental analysis. Electrochemical measurements coupled to spectroelectrochemistry and EPR spectroscopy proved that in the bis(allenylidene) complexes an electronic communication is present between either the two allenylidene bridges or the two metal centers, enticing extended intramolecular electronic mobility.
Description: 
22269
URI: http://hdl.handle.net/20.500.12779/5059
ISSN: 0276-7333
DOI: 10.1021/om0492193
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