Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/5041
Title: Redox control of light-induced platinum-cluster-to-iron charge transfer in a bis(ferrocenylethynyl)-substituted hexanuclear platinum derivative
Authors: Albinati, A.
Fabrizi De Biani, Fabrizia 
Leoni, P.
Marchetti, L.
Pasquali, M.
Rizzato, S.
Zanello, Piero
Issue Date: 2005
Project: None 
Journal: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Abstract: 
Compound [Pt6(μ-PtBu2)4(CO)Fc2] is prepared in good yields by the CuI-catalyzed coupling of two equivalents of ethynylferrocene with the hexanuclear cluster [Pt6(μ-PtBu2)4(CO)4Cl2]. Electrochemical and spectroelectrochemical data show the presence of photoelectrochemically triggered electron transfer from the {Pt6} core to the peripheral ferrocenyl subunits.
Description: 
40221
URI: http://hdl.handle.net/20.500.12779/5041
ISSN: 1433-7851
DOI: 10.1002/anie.200501714
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