Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4945
Title: Electron transfer and CO addition to polynitrido cobalt carbonyl clusters: Parallel pathways for conversion of the [Co10N2(CO)(19)](4-) anion to the novel [Co11N2(CO)(21)](3-) anion
Authors: Fumagalli, A.
Ulivieri, P.
Costa, M.
Crispu, O.
Della Pergola, R.
Fabrizi De Biani, Fabrizia 
Laschi, Franco 
Zanello, Piero
Macchi, P.
Sironi, A.
Issue Date: 2004
Project: None 
Journal: INORGANIC CHEMISTRY
Abstract: 
The redox aptitude of the dinitrido anion [Co10N2(CO)19]4- has been tested from both chemical and electrochemical points of view, together with its reactivity toward CO that induces disproportionation. In any case, through a remarkable overlapping of intermediate steps, the new anion [Co11N2(CO)21]3- (4) is eventually obtained. A detailed study of the pathways to 4 allowed the identification of three labile intermediates by their characteristic IR spectra as well as their electrochemical and paramagnetic properties. The unprecedented structure of trianion 4 has been studied in details in two different crystalline salts.
Description: 
40228
URI: http://hdl.handle.net/20.500.12779/4945
ISSN: 0020-1669
DOI: 10.1021/ic035133a
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