Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4904
Title: Cavity Effects on the Enantioselectivity of Chiral Amido[4]resorcinarene Stereoisomers
Authors: B., Botta
D., Subissati
Tafi, Andrea 
G., DELLE MONACHE
A., Filippi
M., Speranza
Issue Date: 2004
Project: None 
Journal: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Abstract: 
Enzyme catalysis plays a crucial role in all biochemicalprocesses. Natural and artificial enzymes normally exhibit ahigh enantioselectivity toward chiral molecules as a consequenceof shape-specific noncovalent attractive and repulsiveintermolecular interactions. An important step toward theelucidation of enzyme mechanisms requires a comprehensivekinetic study using simplified models under conditions, suchas the gas phase, where the molecule/receptor interactions arenot perturbed by medium effects. In this study we report a comparative gas-phase study along these lines.
Description: 
19534
URI: http://hdl.handle.net/20.500.12779/4904
ISSN: 1433-7851
DOI: 10.1002/anie.200460663
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