Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4825
Title: Synthesis and molecular modelling studies of resorcin[4]arene-capped porphyrins
Authors: Botta, B
Ricciardi, P
Galeffi, C
Botta, Maurizio 
Tafi, Andrea 
Pogni, Rebecca 
Iacovino, R
Garella, I
DI BLASIO, B
DELLE MONACHE, G.
Issue Date: 2003
Project: None 
Journal: ORGANIC & BIOMOLECULAR CHEMISTRY
Abstract: 
Three new resorcin[4]arene-capped porphyrins (3, 5 and 7) different in the porphyrin skeleton, in the linking arms and in the cavity dimensions, have been synthesised. Molecular modelling calculations explored the conformations and the cavity size of the three compounds and showed that their hydrophobic pockets can accommodate one molecule of water or methane (3 and 5), or benzene (7) without any distortion. Notably, the capped porphyrin 5 was able to inhibit the oxidation of Co(II) to Co(III), whereas compound 7 did it only partially.
Description: 
37619
URI: http://hdl.handle.net/20.500.12779/4825
ISSN: 1477-0520
DOI: 10.1039/b303741j
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