Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4783
Title: Metallacarborane-based nanostructures: A carbon-wired planar octagon
Authors: Yao, H.
Sabat, M.
Grimes, R. N.
Fabrizi De Biani, Fabrizia 
Zanello, Piero
Issue Date: 2003
Project: None 
Journal: ANGEWANDTE CHEMIE. INTERNATIONAL EDITION
Abstract: 
A planar C16B8 octagonal macrocycle that incorporates four identical metallacarborane units, linked by four diethynyl chains, has been prepared from a monomeric cobaltacarborane through a designed multistep synthesis (see picture). The air-stable molecule undergoes stepwise electrochemical reduction in TH F solution to generate tuono-, di-, and tetraanions, with the cyclic and square-wave voltammetric data indicating significant electron delocalization in the ring system.
Description: 
40266
URI: http://hdl.handle.net/20.500.12779/4783
ISSN: 1433-7851
DOI: 10.1002/anie.200390255
Appears in Collections:Publications

Show full item record

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.