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|Title:||Conformational Analysis of the N-Arachinylethanolamide (Anandamide) using Nuclear Magnetic Resonance and Theoretical Calculations||Authors:||Bonechi, Claudia
|Keywords:||NMR; anandamide; conformational study; theoretical calculation||Issue Date:||2001||Project:||None||Journal:||MAGNETIC RESONANCE IN CHEMISTRY||Abstract:||
The conformational properties of cis-5,8,11,14-eicosatetraenoylethanolamide (anandamide) were analysedby the combined use of NMRexperimental results plus molecular simulations. The structure of anandamidewas found to be a predominantly linear with a seven-atom ring of the ethanolamine group havinga hydrogen bond which stabilizes the molecule. The vinylic group present has a cis conformation insolution. The terminal chain has a linear conformation and undergoes isotropic fast motion typical of thisstructure
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