Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4482
Title: Synthesis, structure, and spectroelectrochemical investigation of novel ternary Co/S(Se)/Sn clusters derived from binary cobalt stannanediyl complexes
Authors: Schneider, J. J.
Hagen, J.
Spickermann, D.
Blaser, D.
Boese, R.
Fabrizi De Biani, Fabrizia 
Laschi, Franco 
Zanello, Piero
Issue Date: 2000
Project: None 
Journal: CHEMISTRY-A EUROPEAN JOURNAL
Abstract: 
Ternary five-vertex arachno-type cobalt-tin-chalcogene clusters are accessible by means of insertion of the chalcogen elements S and Se into the unbridged Co−Sn bond of the stannanediyl cobalt complexes [(η5-CpR)Co−Sn{CH(SiMe3)2}2] (1-3). They display a rich spectroelectrochemistry. CV and EPR measurements reveal that the relevant HOMO orbitals are strongly transition metal centered.
Description: 
40312
URI: http://hdl.handle.net/20.500.12779/4482
ISSN: 0947-6539
DOI: 10.1002/(SICI)1521-3765(20000117)6:2<237
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