Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/4479
Title: EPR Characterization of Mono(Thiosemicarbazones) Copper(II) Complexes. Note II
Authors: Pogni, Rebecca 
Baratto, Maria Camilla 
Diaz, A.
Basosi, Riccardo 
Keywords: Mono(thiosemicarbazone), Copper(II) complexes, Electron paramagnetic resonance spectroscopy, Structure
Issue Date: 2000
Project: None 
Journal: JOURNAL OF INORGANIC BIOCHEMISTRY
Abstract: 
Several derivatives of thiosemicarbazones and their iron and copper complexes have been studied for their cytotoxicity and inhibiting activity against DNA synthesis. In the present work complexes formed in H2O–DMSO solution between copper(II) and the acetophenone thiosemicarbazone (ATSC) and the o-aminobenzaldehyde thiosemicarbazone (o-NH2TSC) have been studied. EPR studies have been performed at different pH values and metal-to-ligand ratios. The spectra have been recorded at both room (298 K) and low temperatures (120 K). A possible relationship between structure and activity is attempted on the basis of the EPR data.
Description: 
38368
URI: http://hdl.handle.net/20.500.12779/4479
ISSN: 0162-0134
DOI: 10.1016/S0162-0134(99)00166-X
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