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|Title:||1,3-diastereocontrol With Bromoallenes - Synthesis of Enantiomerically Pure Beta-branched Alpha-amino-acids||Authors:||F., Daniello
C. G., Wermuth
|Issue Date:||1994||Project:||None||Journal:||TETRAHEDRON LETTERS||Abstract:||
Bromoallenes 3a and 3b derived from (D)-Serine undergo S(N)2' alkylation with organo copper reagents to give alkynyl amino alcohol derivatives. These compounds can be further transformed into blanched enantiomerically enriched alpha-amino acids as, for example (L)-Isolcucine and (L)-Alloisoleucine.
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