Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3958
Title: A Modification of the Hiyama Reaction - Synthesis of Homo Allylic Amines From Imines and Allylic Bromides In the Presence of Crcl2
Authors: M., Giammaruco
Taddei, Maurizio 
P., Ulivi
Issue Date: 1993
Project: None 
Journal: TETRAHEDRON LETTERS
Abstract: 
Arylic and alkylic imines, activated with BF3.OEt2 react with different allylic bromides in the presence of CrCl2 to give the corresponding homo allylic amines. The reaction can be performed in a single step starting from the aldehyde and the amine, in the presence of molecular sieves (4 angstrom), in a sort of amino-allylation of aldehydes. With the imine derived from benzaldehyde and (S)-valine a good diastereomeric excess (86%) is obtained.
Description: 
45947
URI: http://hdl.handle.net/20.500.12779/3958
ISSN: 0040-4039
DOI: 10.1016/S0040-4039(00)73656-2
Appears in Collections:Publications

Show full item record

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.