Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3955
Title: Synthesis of (-)-heliotridane and (-)-isoretronecanol Via Diastereoselective Conjugate Addition of Organocuprates To An Enoate Deriving From Proline
Authors: S., Lecoz
A., Mann
F., Thareau
Taddei, Maurizio 
Issue Date: 1993
Project: None 
Journal: HETEROCYCLES
Abstract: 
A synthesis of the pyrrolizidine alkaloids (-)-heliotridane and (-)-isoretronecanol and their epimers is described. The key step involves a daistereoselective conjugate addition of organocuprates to (2S)-N-(tert-butoxycarbonyl)-2-[(E)-3'-methoxy-3'-oxo-1'-propenyl]pyrrolidine (2) deriving from (S)-proline.
Description: 
45948
URI: http://hdl.handle.net/20.500.12779/3955
ISSN: 0385-5414
Appears in Collections:Publications

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