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|Title:||Acyclic Stereoselection In the Reaction of Chiral Allylsilanes With Electrophiles||Authors:||C., Nativi
|Issue Date:||1991||Project:||None||Journal:||TETRAHEDRON LETTERS||Abstract:||
The presence of a stereocenter close to the double bond of an allylsilane has an influence on the stereochemistry of the reaction with electrophiles. The stereoselectivity follows the rule of electrophilic attack on a trigonal carbon adjacent to a stereogenic center proposed by Houk. From chiral allylsilanes and achiral aldehydes it is possible to prepare homo allyl alcohols with three stereocenters with a good stereoselectivity.
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