Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3864
Title: Acyclic Stereoselection In the Reaction of Chiral Allylsilanes With Electrophiles
Authors: C., Nativi
G., Palio
Taddei, Maurizio 
Issue Date: 1991
Project: None 
Journal: TETRAHEDRON LETTERS
Abstract: 
The presence of a stereocenter close to the double bond of an allylsilane has an influence on the stereochemistry of the reaction with electrophiles. The stereoselectivity follows the rule of electrophilic attack on a trigonal carbon adjacent to a stereogenic center proposed by Houk. From chiral allylsilanes and achiral aldehydes it is possible to prepare homo allyl alcohols with three stereocenters with a good stereoselectivity.
Description: 
45938
URI: http://hdl.handle.net/20.500.12779/3864
ISSN: 0040-4039
DOI: 10.1016/S0040-4039(00)74278-X
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