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|Title:||EPR and Electrochemical study of Copper Complexes with Phenanthrolines and Cinnamate ligands||Authors:||ZORODDU M., A
PILO M., I
|Keywords:||EPR; electrochemical experiments; Phenanthrolines; copper complexes||Issue Date:||1991||Project:||None||Journal:||INORGANICA CHIMICA ACTA||Abstract:||
Solid state and solution EPR and electrochemical studies have been carried out on a series of complexes of copper(II) with differently substituted Phenanthrolines and cinnamate ligands. Spectra were recorded on binary complexes with cinnamate ligand and on a series of ternary complexes with the same anion and 1,10-Phenanthroline, 2,9-dimethyl-1,10-o-Phenanthroline or 4,7-dimethyl-1,10-o-Phenanthroline additional ligands, respectively. The electrochemistry of the same copper complexes was studied in N,N-dimethylformamide solvent. The results of both EPR and electrochemical experimetns can be correlated with electronic and steric effects attributable to the methyl substituents on the Phenanthroline ligand
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