Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3849
Title: Stereoselective Vinylation of Amino Aldehydes Using 2-trimethylsilylethylidentriphenylphosphorane
Authors: M., Franciotti
A., Mann
Taddei, Maurizio 
Issue Date: 1991
Project: None 
Journal: TETRAHEDRON LETTERS
Abstract: 
2-Trimethylsilylethylidentriphenylphosphorane reacts stereoselectively with alpha-amino aldehydes giving the Cram chelation controlled product of vinylation of the carbonyl group. The olefinic 1,2-amino alcohols obtained with this reaction are important intermediates for the preparation of peptides analogues and they were employed for the preparation of N-Boc-statine.
Description: 
45940
URI: http://hdl.handle.net/20.500.12779/3849
ISSN: 0040-4039
DOI: 10.1016/S0040-4039(00)93602-5
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