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|Title:||Stereoselective Vinylation of Amino Aldehydes Using 2-trimethylsilylethylidentriphenylphosphorane||Authors:||M., Franciotti
|Issue Date:||1991||Project:||None||Journal:||TETRAHEDRON LETTERS||Abstract:||
2-Trimethylsilylethylidentriphenylphosphorane reacts stereoselectively with alpha-amino aldehydes giving the Cram chelation controlled product of vinylation of the carbonyl group. The olefinic 1,2-amino alcohols obtained with this reaction are important intermediates for the preparation of peptides analogues and they were employed for the preparation of N-Boc-statine.
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