Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3778
DC FieldValueLanguage
dc.contributor.authorM., Gullottien_us
dc.contributor.authorL., Casellaen_us
dc.contributor.authorA., Pintaren_us
dc.contributor.authorE., Suardien_us
dc.contributor.authorP., Zanelloen_us
dc.contributor.authorMangani, Stefanoen_us
dc.date.accessioned2021-03-30T14:35:45Z-
dc.date.available2021-03-30T14:35:45Z-
dc.date.issued1989-
dc.identifier.issn0300-9246en_US
dc.identifier.urihttp://hdl.handle.net/20.500.12779/3778-
dc.description48002en_US
dc.description.abstractThe copper(I) and zinc(II) analogues of a series of CuII–N2S2 complexes of bis(imine) ligands derived from the condensation of 3-formyl-1 -phenyl-2(1H)-pyridinethione and diamines are described, together with the electrochemical properties of the couple CuII–CuI and the crystal structure of the copper(II) complex of the ligand obtained from 1,3-propylenediamine. The complex crystallizes in the centrosymmetric space group P[1 with combining macron] with a= 16.111(4), b= 11.194(4), c= 8.681(2)Å, α= 106.81(2), β= 96.47(2), γ= 95.38(2)°, Z= 2, and R= 0.073 for 3 328 reflections with I > 3σ(I). The copper atom is equatorially co-ordinated to two imine nitrogens [Cu–N 1.980(5) and 1.989(5)Å] and two sulphur atoms [Cu–S 2.259(2) and 2.288(2)Å], and weakly bound to an oxygen atom of a perchlorate anion in an axial position [Cu–O 2.635(5)Å]. The CuN2S2 centre displays a slightly tetrahedrally distorted planar arrangement.en_US
dc.language.isoenen_US
dc.relationNoneen_US
dc.relation.ispartofJOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONSen_US
dc.subjectx-ray; crystal structure; copper; zinc; complexen_US
dc.titleSpectroscopic and Electrochemical Study of Copper and Zinc-complexes With A N2s2 Ligand Donor Set - Crystal-structure of the Copper(ii) Complex Derived From 1,3-propylenediamine and 3-formyl-1-phenyl-2(1h)-pyridinethioneen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/dt9890001979en_US
dc.identifier.scopus2-s2.0-37049067774en_US
dc.identifier.isiWOS:A1989AU59900014en_US
dc.description.firstpage1979en_US
dc.description.lastpage1986en_US
dc.description.thirdmissionNot applicableen_US
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeArticle-
item.fulltextNo Fulltext-
crisitem.author.orcid0000-0003-4824-7478-
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