Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3771
Title: Sensitivity analysis for liquid-phase multifrequency EPR spectra of Cu2+ square-planar complexes
Authors: J. S., Hyde
PASENKIEWICZ GIERULA, M
Basosi, Riccardo 
Froncisz, W
Antholine, W. E.
Issue Date: 1989
Project: None 
Journal: JOURNAL OF MAGNETIC RESONANCE
Abstract: 
A computer-based analytical study is presented of the sensitivity of EPR spectra from square-planar copper complexes to the input parameters in the spin Hamiltonian as a function of rotational correlation time and microwave frequency. X band is found to be a good choice of microwave frequency using either χ2 or the modulus integrated over the spectrum. Universal curves are presented that permit relating parameter sensitivities over a wide range of experimental conditions. The study develops techniques for computer analysis of multifrequency EPR spectra (109 to 1011 Hz) to find values for the magnetic and motional properties with minimum uncertainty.
Description: 
18638
URI: http://hdl.handle.net/20.500.12779/3771
ISSN: 0022-2364
DOI: 10.1016/0022-2364(89)90165-0
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