Please use this identifier to cite or link to this item: http://hdl.handle.net/20.500.12779/3737
Title: Polynuclear Zinc(ii) Complexes With Large Polyazacycloalkanes - Equilibrium Studies and Crystal-structure of the Binuclear [zn2([30]anen10)(ncs)](clo4)3 Complex
Authors: A., Bencini
A., Bianchi
E., Garciaespana
Mangani, Stefano 
M., Micheloni
P., Orioli
P., Paoletti
Keywords: x-ray; crystal structure; macrocycle
Issue Date: 1988
Project: None 
Journal: INORGANIC CHEMISTRY
Abstract: 
Large polyazacycloalkanes, defined as saturated aza macrocycles with more than six secondary nitrogens as donor atoms, are interesting ligand molecules. The cyclic nature, the elevated number of donor atoms available, and the molecular flexibility make these ligands very versatile for the formation of polynuclear metal complexes. In earlier papers we have reported the synthesis and the copper(I1) complexes of many large polya z a c y ~ l o a l k a n e s . ~I-n~ this paper we have investigated the formation equilibria of binuclear zinc(I1) complexes of the three large polyazacycloalkanes 1,4,7,10,13,16,19,22,25-nonaazacycloheptacosane ( [27]aneN9), 1,4,7,10,13,16,19,22,25,28-decaazacyclotriacontane ( [30]aneNlo),a nd 1,4,7,10,13,16,19,22,25,2l8-u,n3 - decazacyclotritriacontane ( [33]aneN11.
Description: 
48008
URI: http://hdl.handle.net/20.500.12779/3737
ISSN: 0020-1669
DOI: 10.1021/ic00279a035
Appears in Collections:Publications

Show full item record

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.