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|Title:||Proton magnetic relaxation mechanisms and solution dynamics of L-histidine||Authors:||Rossi, Claudio
|Issue Date:||1983||Project:||None||Journal:||JOURNAL OF THE CHEMICAL SOCIETY. FARADAY TRANSACTIONS I||Abstract:||
Longitudinal and transverse proton relaxation rates have been measured for L-histidine in water solution. From a comparison of the former, measured in the selective and non-selective modes, it was found that the dipolar relaxation mechanism dominates the proton relaxation process. Molecular and internal motions have been quantified on the basis of a 'jump' relaxation model. Complex relaxation behaviour has been observed for protons of the histidyl species.
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