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|Title:||Electron spin relaxation and frequency dependent lineshape analysis of the 5'-ATP-Mn(II)-Trp system||Authors:||Laschi, Franco
|Issue Date:||1979||Project:||None||Journal:||CHEMICAL PHYSICS LETTERS||Abstract:||
A frequency-dependent lineshape analysis of the ESR spectra of ternary systems in solution has been carried out. The 5′-ATP—Mn(II)—Trp complex has been chosen as a model system. The analysis points out the presence of inverted spectra at both X- and Q-bands. The lineshape is described by a distribution of configurational sites, Yl(ω) = ΣkPkYk(H). The temperature dependence of the ESR linewidth has also been investigated and is discussed in terms of chemical equilibria and correlation times.
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